Batteries achieve the desired operating voltage by connecting several cells in series; each cell adds its voltage potential to derive at the total terminal voltage. Some packs may consist of a combination of series and parallel connections. Laptop batteries commonly have four 3.6V Li-ion cells in series to achieve a nominal voltage 14.4V and two in parallel to boost the capacity from 2,400mAh to 4,800mAh. Such a configuration is called 4s2p, meaning four cells in series and two in parallel.

It is important to use the same battery type with equal voltage and capacity (Ah) and never to mix different makes and sizes. A weaker cell would cause an imbalance, as a battery is only as strong as the weakest link in the chain.

Single Cell Applications

The single-cell configuration is the simplest battery pack; the cell does not need matching and the protection circuit on a small Li-ion cell can be kept simple. Typical examples are mobile phones and tablets with one 3.60V Li-ion cell. Other uses of a single cell are wall clocks, which typically use a 1.5V alkaline cell, wristwatches and memory backup, most of which are very low power applications.

Series Connection

Portable equipment needing higher voltages use battery packs with two or more cells connected in series.

Figure 2: Series connection of four cells (4s).
Adding cells in a string increases the voltage; the capacity remains the same.

High voltage batteries keep the conductor size small. Cordless power tools run on 12V and 18V batteries; high-end models use 24V and 36V. Most e-bikes come with 36V Li-ion, some are 48V. The car industry wanted to increase the starter battery from 12V (14V) to 36V, better known as 42V, by placing 18 lead acid cells in series.

Some mild hybrid cars run on 48V Li-ion and use DC-DC conversion to 12V for the electrical system.

Parallel Connection

If higher currents are needed and larger cells are not available or do not fit the design constraint, one or more cells can be connected in parallel. Most battery chemistries allow parallel configurations with little side effect.

Figure 4: Parallel connection of four cells (4p).

With parallel cells, capacity in Ah and runtime increases while the voltage stays the same.

Series/parallel Connection

The series/parallel configuration shown in Figure 6 enables design flexibility and achieves the desired voltage and current ratings with a standard cell size. The total power is the product of voltage-times-current; four 3.6V (nominal) cells multiplied by 3,400mAh produce 12.24Wh. Four 18650 Energy Cells of 3,400mAh each can be connected in series and parallel as shown to get 7.2V nominal and 12.24Wh. The slim cell allows flexible pack design but a protection circuit is needed.

Figure 6: Series/ parallel connection of four cells (2s2p).

This configuration provides maximum design flexibility. Paralleling the cells helps in voltage management.

Safety devices in Series and Parallel Connection

Positive Temperature Coefficient Switches (PTC) and Charge Interrupt Devices (CID) protect the battery from overcurrent and excessive pressure. While recommended for safety in a smaller 2- or 3-cell pack with serial and parallel configuration, these protection devices are often being omitted in larger multi-cell batteries, such as those for power tool.

 Simple Guidelines for Using Household Primary Batteries

• Keep the battery contacts clean. A four-cell configuration has eight contacts and each contact adds resistance (cell to holder and holder to next cell).
• Never mix batteries; replace all cells when weak. The overall performance is only as good as the weakest link in the chain.
• Observe polarity. A reversed cell subtracts rather than adds to the cell voltage.
• Remove batteries from the equipment when no longer in use to prevent leakage and corrosion. This is especially important with zinc-carbon primary cells.
• Do not store loose cells in a metal box. Place individual cells in small plastic bags to prevent an electrical short. Do not carry loose cells in your pockets.
• Keep batteries away from small children. In addition to being a choking hazard, the current-flow of the battery can ulcerate the stomach wall if swallowed. The battery can also rupture and cause poisoning.
• Do not recharge non-rechargeable batteries; hydrogen buildup can lead to an explosion. ·Perform experimental charging only under supervision.

Simple Guidelines for Using Secondary Batteries

• Observe polarity when charging a secondary cell. Reversed polarity can cause an electrical short, leading to a hazardous condition.
• Remove fully charged batteries from the charger. A consumer charger may not apply the correct trickle charge when fully charged and the cell can overheat.
• Charge only at room temperature.

Date:APRIL 22, 2019

Source:Columbia University School of Engineering and Applied Science

An artificial boron nitride (BN) film is chemically and mechanically robust against lithium. It electronically isolates lithium aluminum titanium phosphate (LATP) from lithium, but still provides stable ionic pathways when infiltrated by polyethylene oxide (PEO), and thus enables stable cycling. Credit: Qian Cheng/Columbia Engineering

The grand challenge to improve energy storage and increase battery life, while ensuring safe operation, is becoming evermore critical as we become increasingly reliant on this energy source for everything from portable devices to electric vehicles. A Columbia Engineering team led by Yuan Yang, assistant professor of materials science and engineering, announced today that they have developed a new method for safely prolonging battery life by inserting a nano-coating of boron nitride (BN) to stabilize solid electrolytes in lithium metal batteries. Their findings are outlined in a new study published by Joule.

While conventional lithium ion (Li-ion) batteries are currently widely used in daily life, they have low energy density, resulting in shorter battery life, and, because of the highly flammable liquid electrolyte inside them, they can short out and even catch fire. Energy density could be improved by using lithium metalto replace the graphite anode used in Li-ion batteries: lithium metal’s theoretical capacity for the amount of charge it can deliver is almost 10 times higher than that of graphite. But during lithium plating, dendrites often form and if they penetrate the membrane separator in the middle of the battery, they can create short-circuits, raising concerns about battery safety.

“We decided to focus on solid, ceramic electrolytes. They show great promise in improving both safety and energy density, as compared with conventional, flammable electrolytes in Li-ion batteries,” says Yang. “We are particularly interested in rechargeable solid-state lithium batteries because they are promising candidates for next-generation energy storage.”

Most solid electrolytes are ceramic, and therefore non-flammable, eliminating safety concerns. In addition, solid ceramic electrolytes have a high mechanical strength that can actually suppress lithium dendrite growth, making lithium metal a coating option for battery anodes. However, most solid electrolytes are unstable against Li—they can be easily corroded by lithium metal and cannot be used in batteries.

The left visual shows that a Lithium aluminum titanium phosphate (LATP) pellet that touches lithium metal will be immediately reduced. The severe side reaction between lithium and solid electrolyte will fail the battery in several cycles. The right shows that an artificial BN film is chemically and mechanically robust against lithium. It electronically isolates LATP from lithium, but still provides stable ionic pathways when infiltrated by polyethylene oxide (PEO), and thus enables stable cycling. Credit: Qian Cheng/Columbia Engineering

“Lithium metal is indispensable for enhancing energy density and so it’s critical that we be able to use it as the anode for solid electrolytes,” says Qian Cheng, the paper’s lead author and a postdoctoral research scientist in the department of applied physics and applied mathematics who works in Yang’s group. “To adapt these unstable solid electrolytes for real-life applications, we needed to develop a chemically and mechanically stable interface to protect these solid electrolytes against the lithium anode. It is essential that the interface not only be highly electronically insulating, but also ionically conducting in order to transport lithium ions. Plus, this interface has to be super-thin to avoid lowering the energy density of batteries.”

To address these challenges, the team worked with colleagues at Brookhaven National Lab and the City University of New York. They deposited 5~10 nm boron nitride (BN) nano-film as a protective layer to isolate the electrical contact between lithium metal and the ionic conductor (the solid electrolyte), along with a trace quantity of polymer or liquid electrolyte to infiltrate the electrode/electrolyte interface. They selected BN as a protective layer because it is chemically and mechanically stable with lithium metal, providing a high degree of electronic insulation. They designed the BN layer to have intrinsic defects, through which lithium ions can pass through, allowing it to serve as an excellent separator. In addition, BN can be readily prepared by chemical vapor deposition to form large-scale (~dm level), atomically thin scale (~nm level), and continuous films.

“While earlier studies used polymeric protection layers as thick as 200 μm, our BN protective film, at only 5~10 nm thick, is record-thin—at the limit of such protection layers—without lowering the energy density of batteries,” Cheng says. “It’s the perfect material to function as a barrier that prevents the invasion of lithium metal to solid electrolyte. Like a bullet-proof vest, we’ve developed a lithium-metal-proof ‘vest’ for unstable solid electrolytes and, with that innovation, achieved long cycling lifetime lithium metal batteries.”

The researchers are now extending their method to a broad range of unstable solid electrolytes and further optimize the interface. They expect to fabricate solid-state batteries with high performance and long-cycle lifetimes.

By and large, lithium batteries bring a wide range of different benefits to the table that are difficult – if not impossible – to replicate in any other way. Also commonly referred to as lithium-metal batteries (due to the fact that they use lithium as an anode), they’re typically capable of offering a very high-charge density (read: longer lifespan) than other alternatives that are on the market today.

For that reason alone, lithium batteries have a wide range of applications in our daily lives, especially for those critical in nature that we tend not to spend too much time thinking about. Specialized types of lithium batteries are used in pacemakers and other implanted medical devices, for example, because they can often last 15 years (or longer) under the right circumstances. They’ve even started to replace traditional alkaline batteries in many everyday devices like clocks, digital cameras, watches, portable data assistants, and more, all thanks to that longer lifespan that minimizes the need to replace the battery over time.

LITHIUM BATTERIES: CYLINDRICAL VERSUS PRISMATIC

Example of cylindrical lithium batteries.

Issues like mechanical vibrations, thermal cycling from charging and discharging, and the mechanical expansion of current conductors are all things that can affect a battery’s lifespan. Therefore, the design of these cylindrical units is intended to help mitigate risk from these and other factors as much as possible.

On the inside of a cylindrical battery, a series of cells are combined and operate in parallel to one another. This is done to help increase both the voltage and the overall capacity of the battery pack.

For these reasons, cylindrical batteries are usually the kind that are found in the aforementioned medical device systems. Smaller, more specially designed cylindrical cells are also commonly found in portable devices like laptop computers. Notably, Tesla also made headlines recently by selecting cylindrical lithium batteries to power its fleet of popular electric cars.

What Are Prismatic Lithium Batteries?

A prismatic lithium battery, on the other hand, features a cell that has been encased in either aluminum or steel, mainly for the purposes of increased stability. This, in turn, creates several key advantages right out of the gate. Because of this unique construction and makeup, prismatic lithium batteries tend to be very thin, very light and offer an effective use of space.

Example of prismatic lithium batteries.

Because the rectangular shape of your average prismatic Li battery offers far better layering than other options, they typically give engineers a higher level of flexibility when designing products that will one day feature prismatic batteries as power sources. Because of that, it should come as no surprise that prismatic batteries are typically found in smartphones, tablets, and similar types of electronic devices where mobility is a major priority.

Due to these properties, modern day prismatic batteries are also commonly used in larger critical applications like energy storage systems and in electric powertrains.

Cylindrical Versus Prismatic Batteries: Breaking Things Down

There’s a reason why cylindrical lithium batteries are the most commonly available (and used) type today. When compared to their prismatic counterparts, they can typically be produced much faster and with a lower cost-per-KWh (kilowatt hour) at the same time. The design itself better supports the types of automation processes that are commonplace in factories and in other manufacturing environments across the country, for example, which only aid in creating a better sense of product consistency and keeping those ultimate costs as low as possible.

One of the major reasons why prismatic cells have increased in popularity over the last few years, however, has to do with their large capacity. That, coupled with their naturally prismatic shape, make it very easy to connect four different cells together to help create something like a 12-volt battery pack.

The prismatic design does come with its own challenges, however, particularly as they relate to what happens if something goes wrong. If one cell in a prismatic battery goes bad for any reason, for example, the entire battery pack that it is a part of is essentially compromised. Because the cells in a cylindrical battery are combined in a series and in parallel, these are the types of problems that designers and other engineers don’t really have to worry about.

Because of the design of cylindrical Li batteries, they also tend to radiate heat (and thus control their own temperature) more easily than their prismatic counterparts. Because of the way that prismatic cells are all placed together, this certainly works to increase the capacity, but it also leaves room for a higher probability of design inconsistency and short circuiting. The larger size of the prismatic cell may also be attractive in certain situations, but it also minimizes the chances that such a battery could be used in a heavily automated environment. That larger cell size also creates perhaps the biggest disadvantage for prismatic batteries: the increased capacity makes it far more difficult for the battery management system to properly regulate heat and prevent the battery itself from overcharging.

As previously stated, the thin form factor of a prismatic battery leads to increased flexibility for product designers – this does, however, create a few disadvantages of its own. It is that very same design that ultimately makes prismatic batteries somewhat difficult and expensive to properly design and manufacturer, which are costs that are almost certainly passed along to consumers. That flexibility has also created a limited number of “standardized” cell sizes, which only adds to difficulty in that regard. This also contributes to a higher than average KWh price as well.

It’s important to note, however, that the topic of costs is also one that comes with a few important caveats. Experts agree that because prismatic cells can often be larger than their cylindrical counterparts and will thus cost more initially, they offer more opportunity for cost reduction in the long-term. Based on that, you may want to think about the cost factor in the following way: is it more important to save money now by going cylindrical, or can you depend on your ability to innovate and potentially save a larger amount of money over time? The answer to that question, of course, is one that only you can answer based on whatever it is you’re trying to do.

Maybe the biggest advantage of cylindrical batteries in most situations is that they are very safe. If the internal pressure of a cylindrical lithium battery grows too high, most of the cells are designed to rupture – thus mitigating safety risks from situations like a fire or an explosion.

In The End

None of this is to say that cylindrical lithium batteries are inherently “better” than their prismatic counterparts, or vice versa. As is often the case with these types of situations, there is no “one-size-fits-all” approach to battery selection. Much of your decision will ultimately come down to the eventual application and the amount of risks and potential disadvantages that you’re willing to accept as a result. There will be some situations where a prismatic battery absolutely makes the most sense. There will be situations where cylindrical batteries seem like the logical choice.

More often than not, choosing the right type of lithium battery to meet your needs will come down to three factors:

The amount of money you’re willing to pay, the effectiveness of the battery you’re trying to unlock, and the safety considerations given the application.

If space isn’t necessarily at a premium and you need to find a cost-effective way to guarantee both performance and longevity, cylindrical batteries offer what you need.

If cost isn’t a factor and you need as much power as possible in an already small space, prismatic is likely the direction you’ll want to head in.

Only by trying to learn as much about these options as possible will you be able to make the best decision given your needs in the moment. Ultimately, your ability to do that successfully is all that matters.