New Lithium-Based Battery Design Makes Use of Greenhouse Gas

TOPICS:Battery TechnologyCarbon DioxideGreen TechnologyMITSustainability
By DAVID L. CHANDLER, MIT NEWS OFFICE SEPTEMBER 22, 2018

This scanning electron microscope image shows the carbon cathode of a carbon-dioxide-based battery made by MIT researchers, after the battery was discharged. It shows the buildup of carbon compounds on the surface, composed of carbonate material that could be derived from power plant emissions, compared to the original pristine surface (inset). Courtesy of the researchers

New lithium-based battery could make use of greenhouse gas before it ever gets into the atmosphere.

A new type of battery developed by researchers at MIT could be made partly from carbon dioxide captured from power plants. Rather than attempting to convert carbon dioxide to specialized chemicals using metal catalysts, which is currently highly challenging, this battery could continuously convert carbon dioxide into a solid mineral carbonate as it discharges.

While still based on early-stage research and far from commercial deployment, the new battery formulation could open up new avenues for tailoring electrochemical carbon dioxide conversion reactions, which may ultimately help reduce the emission of the greenhouse gas to the atmosphere.

The battery is made from lithium metal, carbon, and an electrolyte that the researchers designed. The findings are described today in the journal Joule, in a paper by assistant professor of mechanical engineering Betar Gallant, doctoral student Aliza Khurram, and postdoc Mingfu He.

Currently, power plants equipped with carbon capture systems generally use up to 30 percent of the electricity they generate just to power the capture, release, and storage of carbon dioxide. Anything that can reduce the cost of that capture process, or that can result in an end product that has value, could significantly change the economics of such systems, the researchers say.

However, “carbon dioxide is not very reactive,” Gallant explains, so “trying to find new reaction pathways is important.” Generally, the only way to get carbon dioxide to exhibit significant activity under electrochemical conditions is with large energy inputs in the form of high voltages, which can be an expensive and inefficient process. Ideally, the gas would undergo reactions that produce something worthwhile, such as a useful chemical or a fuel. However, efforts at electrochemical conversion, usually conducted in water, remain hindered by high energy inputs and poor selectivity of the chemicals produced.

Gallant and her co-workers, whose expertise has to do with nonaqueous (not water-based) electrochemical reactions such as those that underlie lithium-based batteries, looked into whether carbon-dioxide-capture chemistry could be put to use to make carbon-dioxide-loaded electrolytes — one of the three essential parts of a battery — where the captured gas could then be used during the discharge of the battery to provide a power output.

This approach is different from releasing the carbon dioxide back to the gas phase for long-term storage, as is now used in carbon capture and sequestration, or CCS. That field generally looks at ways of capturing carbon dioxide from a power plant through a chemical absorption process and then either storing it in underground formations or chemically altering it into a fuel or a chemical feedstock.

Instead, this team developed a new approach that could potentially be used right in the power plant waste stream to make material for one of the main components of a battery.

While interest has grown recently in the development of lithium-carbon-dioxide batteries, which use the gas as a reactant during discharge, the low reactivity of carbon dioxide has typically required the use of metal catalysts. Not only are these expensive, but their function remains poorly understood, and reactions are difficult to control.

By incorporating the gas in a liquid state, however, Gallant and her co-workers found a way to achieve electrochemical carbon dioxide conversion using only a carbon electrode. The key is to preactivate the carbon dioxide by incorporating it into an amine solution.

“What we’ve shown for the first time is that this technique activates the carbon dioxide for more facile electrochemistry,” Gallant says. “These two chemistries — aqueous amines and nonaqueous battery electrolytes — are not normally used together, but we found that their combination imparts new and interesting behaviors that can increase the discharge voltage and allow for sustained conversion of carbon dioxide.”

They showed through a series of experiments that this approach does work, and can produce a lithium-carbon dioxide battery with voltage and capacity that are competitive with that of state-of-the-art lithium-gas batteries. Moreover, the amine acts as a molecular promoter that is not consumed in the reaction.

The key was developing the right electrolyte system, Khurram explains. In this initial proof-of-concept study, they decided to use a nonaqueous electrolyte because it would limit the available reaction pathways and therefore make it easier to characterize the reaction and determine its viability. The amine material they chose is currently used for CCS applications, but had not previously been applied to batteries.

This early system has not yet been optimized and will require further development, the researchers say. For one thing, the cycle life of the battery is limited to 10 charge-discharge cycles, so more research is needed to improve rechargeability and prevent degradation of the cell components. “Lithium-carbon dioxide batteries are years away” as a viable product, Gallant says, as this research covers just one of several needed advances to make them practical.

But the concept offers great potential, according to Gallant. Carbon capture is widely considered essential to meeting worldwide goals for reducing greenhouse gas emissions, but there are not yet proven, long-term ways of disposing of or using all the resulting carbon dioxide. Underground geological disposal is still the leading contender, but this approach remains somewhat unproven and may be limited in how much it can accommodate. It also requires extra energy for drilling and pumping.

The researchers are also investigating the possibility of developing a continuous-operation version of the process, which would use a steady stream of carbon dioxide under pressure with the amine material, rather than a preloaded supply the material, thus allowing it to deliver a steady power output as long as the battery is supplied with carbon dioxide. Ultimately, they hope to make this into an integrated system that will carry out both the capture of carbon dioxide from a power plant’s emissions stream, and its conversion into an electrochemical material that could then be used in batteries. “It’s one way to sequester it as a useful product,” Gallant says.

“It was interesting that Gallant and co-workers cleverly combined the prior knowledge from two different areas, metal-gas battery electrochemistry and carbon-dioxide capture chemistry, and succeeded in increasing both the energy density of the battery and the efficiency of the carbon-dioxide capture,” says Kisuk Kang, a professor at Seoul National University in South Korea, who was not associated with this research.

“Even though more precise understanding of the product formation from carbon dioxide may be needed in the future, this kind of interdisciplinary approach is very exciting and often offers unexpected results, as the authors elegantly demonstrated here,” Kang adds.

MIT’s Department of Mechanical Engineering provided support for the project.

Publication: Aliza Khurram, et al., “Tailoring the Discharge Reaction in Li-CO2 Batteries through Incorporation of CO2 Capture Chemistry,” Joule, 2018; doi:10.1016/j.joule.2018.09.002

 

World’s Most Efficient Lithium-Sulfur Battery Developed – Powers Smartphone for 5 Days

Imagine having access to a battery, which has the potential to power your phone for five continuous days, or enable an electric vehicle to drive more than 1000km without needing to “refuel.” Monash University researchers are on the brink of commercializing the world’s most efficient lithium-sulfur (Li-S) battery, which could outperform current market leaders by more than four times, and power Australia and other global markets well into the future. Dr. Mahdokht Shaibani from Monash University’s Department of Mechanical and Aerospace Engineering led an international research team that developed an ultra-high capacity Li-S battery that has better performance and less environmental impact than current lithium-ion products.

The researchers have an approved filed patent (PCT/AU 2019/051239) for their manufacturing process, and prototype cells have been successfully fabricated by German R&D partners Fraunhofer Institute for Material and Beam Technology.

Associate Professor Matthew Hill, Dr. Mahdokht Shaibani and Professor Mainak Majumder. Credit: Monash University

Some of the world’s largest manufacturers of lithium batteries in China and Europe have expressed interest in upscaling production, with further testing to take place in Australia in early 2020.

The study was published in Science Advances today (Saturday, January 4, 2020) — the first research on Li-S batteries to feature in this prestigious international publication.

Professor Mainak Majumder said this development was a breakthrough for Australian industry and could transform the way phones, cars, computers, and solar grids are manufactured in the future.

“Successful fabrication and implementation of Li-S batteries in cars and grids will capture a more significant part of the estimated $213 billion value chain of Australian lithium, and will revolutionize the Australian vehicle market and provide all Australians with a cleaner and more reliable energy market,” Professor Majumder said.

“Our research team has received more than $2.5 million in funding from government and international industry partners to trial this battery technology in cars and grids from this year, which we’re most excited about.”

Using the same materials in standard lithium-ion batteries, researchers reconfigured the design of sulfur cathodes so they could accommodate higher stress loads without a drop in overall capacity or performance.

Inspired by unique bridging architecture first recorded in processing detergent powders in the 1970s, the team engineered a method that created bonds between particles to accommodate stress and deliver a level of stability not seen in any battery to date.

Attractive performance, along with lower manufacturing costs, abundant supply of material, ease of processing and reduced environmental footprint make this new battery design attractive for future real-world applications, according to Associate Professor Matthew Hill.

“This approach not only favors high-performance metrics and long cycle life, but is also simple and extremely low-cost to manufacture, using water-based processes, and can lead to significant reductions in environmentally hazardous waste,” Associate Professor Hill said.

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How To Properly Dispose Or Recycle Lithium Batteries

Recycle-Lithium-Batteries

According to the Environmental Protection Agency, billions of batteries find their way into landfills every year.

 

These batteries contain toxic substances which can then leech into the earth and water supplies. Fortunately, this negative impact on the environment can be avoided by battery recycling.

 

Did you know that you can recycle lithium batteries? You can, and it’s easier than you might think. Keep reading to learn more about the only safe way to get rid of old batteries.

 

Why Recycle Batteries

Before we go any further, let’s take a quick look at why it’s important to recycle batteries. When you understand why you’re doing something, you’re more likely to continue doing it.

Recycle-Lithium-Batteries

Here are some of the reasons why you should be recycling old batteries:

 

  • Conserves natural resources
  •  Reduces the amount of waste in landfills
  • Prevents pollution created by the collection of raw materials
  •  Creates new jobs in the recycling and manufacturing industries
  • Saves energy
  •  Avoids polluting the environment and groundwater supplies

Many of these benefits come from the fact that metals such as aluminum, nickel, and copper can all be harvested from old batteries. These can then be used in other ways and new metals don’t have to be taken from the earth.

 

What to Do Before Taking in Batteries

Before you take your batteries somewhere to recycle them, there are a few things you’ll want to do.

 

First and foremost, you need to keep your batteries out of your regular trash and recycling bin. Lithium batteries can cause sparks, even if they’re completely dead. This is why you want to avoid putting them with other recyclables.

 

To prevent them from sparking, cover the terminals or ends with electrical tape. It’s a good idea to get into the habit of doing this as soon as a battery is removed so it won’t cause any problems.

 

The other thing you want to do before you pack up your old batteries to recycle is to call ahead. You want to make sure the place you’re taking them accepts the type of battery you have so you don’t waste a trip out there.

 

You also need to ask about fees. Some places will charge a fee to recycle batteries for you whereas other places do it for free. Asking in advance will help you avoid an unpleasant surprise.

 

Where to Recycle Batteries

Recycling lithium batteries is as easy as finding a place that will take them. Here are a few resources you can use to recycle lithium batteries:

 

Recycling Center

One of the best places to take your batteries to where there’s a good chance they’ll take them is a local recycling center. Not every recycling center takes every type of battery, so this is one you’ll definitely want to call before going.

 

A quick search online should allow you to find several recycling centers near you so you can find one that will take your old batteries.

 

Household Hazardous Waste Center

If you’re unfortunate enough to not have a recycling center near you that will take your lithium batteries, you should be able to find a household hazardous waste center.

 

This will require another online query which should lead you to the right place that will definitely take your old batteries.

 

Scrap Yards

To make your trip worth it, you may consider taking your old batteries to a scrap yard. Many of these locations will purchase them from you because they can remove the metals from them and make a profit.

 

This is particularly great for hobbyists who have several large batteries lying around that are in need of recycling.

 

Scrap yards don’t often take alkaline batteries, so if you also have some smaller batteries saved up from various electronics, you’ll have to visit a couple of places to get rid of all of your batteries at once.

 

Local Library or Community Center

Sometimes, a city or local community will have a battery drive or else a specific location where you can drop off batteries to be recycled for you. Ask at your local library or community center for more information about this.

 

In most cases, they primarily take smaller household batteries and other used electronics rather than larger batteries. For this reason, you’ll want to double-check that your larger vehicle batteries will be accepted.

 

Because of how close these places generally are to you compared to recycling centers, this can be the most convenient option.

 

Electronic and Hardware Stores

Here are some stores that may accept batteries for recycling:

 

  • Staples
  •  Best Buy
  • Home Depot
  • Lowes

As you can imagine, hardware stores are more likely to accept larger batteries since they sell them for tools and smaller vehicles.

 

Electronic stores may only accept smaller batteries used in cell phones and other electronics, so you’ll definitely want to ask before taking them there.

 

It’s also important to keep in mind that not every store location offers this service. Call ahead and ask about the specific types of batteries you’re looking to recycle before showing up with them.

Why There Are Still Some Lithium-ion Batteries That Explode Up to Today?

There might be a battery explosion when internal electrical parts short-circuit, when mechanical issues occur after a fall or an accident, or when they is installation error. All of these failures happen when one side of the battery is heated up and cannot lower down the high temperature fast enough, creating a continuous reaction that generates more and more heat. This kind of snowball process is usually termed as thermal runaway.

Introduction

The process can occur in just milliseconds. This has attracted much attention from the press. But it turns out that not all batteries are equally likely to fail. Any energy storage device carries a risk, as demonstrated in the latest moment on 15th March 2017, involving a pair of headphones exploding on a plane. Many batteries come along with a safety risk, and battery manufacturers are supposed to meet safety requirements.

Himax - ICR 18650 Battery-37v-5000mah

Even though Lithium-ion batteries are safe, there are millions of customers using then so failures are bound to occur. A one-in-200,000 mechanical failure that happened in 2006 caused a recall of close to six million lithium-ion packs (Battery University).
Specialists of the lithium-ion batteries comment that on rare occasion microscopic metal particles may touch with other parts of the battery cell, causing a short circuit with in the cell.

So why do people and businesses still use them?

Lithium-ion batteries are super-efficient. They keep large capacity of energy in a small space and can keep electronic gadgets working for a long time. Li-ion power cells are also ranked highly in technology. The earliest rechargeable lithium-ion batteries were made for Handy-cams 25 years ago, and now there are many battery suppliers around the globe.

But unlike most advanced technologies, they get volatile with time. This is mainly due to the fact that we want higher-capacitydable batteries in small packages at affor prices. The symptoms may be the similar as they explode but a lot of other factors might be contributing to lithium-ion’s explosions.

These include;

Production Flaws

With all these exploding batteries, the first diagnosis is something must be wrong with the ways the battery is manufactured. Many people might think like that, but Samsung Note 7 issue illustrates that pinpointing the key flaw is not very easy. The initial recall involved devices that had batteries made by Samsung, the ones that did not have enough room between the battery’s protective pouch and electrodes. The squeeze tilted the electrodes in some batteries, leading them to short-circuit. But once the devices were recalled, replacing them with safer batteries from another firm had different issues. Many were not wrapped well, while others had ragged edges inside that caused damage to the main separator. That also caused short circuiting, but for entirely different reasons.

User-Supplied Damage

Even if a device is designed well, continuous dropping and subjecting it to long-term wear and tear can cause damage to the volatile energy source. The best way to tell if your battery is damaged is if it looks all swollen—evidence that the chemicals inside the battery are producing too much gas. That swelling also creates its own stress with the battery housing, which could result to a rupture. Unfortunately, a lot of devices today have a sealed-in battery, and taking the device apart to inspect it involves nullifying the warranty. If the external package of any device appears to be pushing apart or feels abnormally hot to the touch, it’s best to be careful and bring it in for inspection.

Battery Design Flow

Most of today’s devices are designed to be as slim, light, and sleek as possible in order to go with the trend. That can cause stress on an otherwise well-built battery, especially a high-capacity cell packed into a tiny body. Pressure from the hardware surrounding the battery can lead to damage to the electrodes and lead to short circuiting. Insufficient venting or thermal management can lead the flammable electrolyte inside the battery to heat up. Once it gets hot, chemical reactions can cause it to heat up even more and spiral out of control. It’s a situation called thermal runaway that often ends in an explosion or fire.

Industry Pressure and Competition

Companies make billions of profits when they save a small amount on each battery. As a result, many lithium-ion battery manufacturers do shortcuts in order to price their cells at affordable prices. The materials may not meet the required quality, causing damage in the already-thin separator. This situation was likely a major cause of the hoverboard fires: The first models on the market were expensive, and their popularity bred knockoffs with cheap prices and even cheaper internals. Crowd funding and low-priced components have democratized the consumer-electronics industry, but savings often come at the expense of safety.

Even though exploding batteries sound scary, they’re actually quite rare. Himax is committed to supply safer lithium batteries to its customers by using LiFePO4 cells in a variety of applications. LiFePO4 is a more stable and safer cathode material.

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Are Hybrid Cars Here to Stay?

The hybrid car is not new – Ferdinand Porsche designed the series-hybrid vehicle in 1898. Called the Lohner-Porsche carriage, the hybrid function served as an electrical transmission rather than power boost. With Mr. Porsche in the driver’s seat, the car broke several Austrian speed records, including the Exelberg Rally in 1901. Another example of an early hybrid was the 1915 Woods Motor Vehicle built in Chicago. The car used a four-cylinder internal combustion engine and an electric motor. Below 15 mph (25 km/h), the electric motor propelled the vehicle; at higher speeds, the gasoline engine kicked in to take the vehicle up to a top speed of 35 mph (55 km/h). As part of the Federal Clean Car Incentive Program, Victor Wouk installed a hybrid drive train in a 1972 GM Buick Skylark but the EPA canceled the program in 1976. Meanwhile, Honda and Toyota have made strong headways by commercializing attractive and fuel-efficient hybrid cars.

The hybrid electric vehicle (HEV) conserves fuel by using an electric motor that assists the internal-combustion engine (IC) on acceleration and harnesses kinetic energy during breaking. Furthermore, the IC motor turns off at stops and during slow travel. When full power is required, both the IC engine and the electric motors engage simultaneously to get maximum boost. This power-sharing scheme offers two advantages; it calls for a smaller IC engine and improves acceleration because the electric motor has excellent torque characteristics.

Most HEVs use a mechanical drive train from the IC engine to the wheels. In this respect, the HEV is similar to an ordinary vehicle with crankshaft, clutch and transmission, with the difference of having an electric motor and a battery. This design is known as a parallel configuration. Most up-and-coming plug-in HEVs use the serial configuration in which the wheels are powered by one or several electric motors. Instead of a mechanical link, the IC engine energizes a generator to produce electricity for the motor(s). Similar to a laptop or a cell phone, the driver plugs the car into the AC outlet for an overnight charge. The typical driving range with a full charge is 20 miles or 32 km. On long trips, the IC engine engages to provide continuous power for the electric motors.

What’s the best battery for the hybrid car?

The early HEV models used lead acid batteries because there was no alternative. Today, Honda and Toyota employ nickel-metal-hydride (NiMH). This chemistry is lighter and environmentally friendlier than lead-based systems. The battery consists of cylindrical cells that are connected in series to attain several hundred volts. The cell strings are suspended in mid air to allow air-cooling. Figure 1 shows a demonstration pack of an early Toyota hybrid car battery.

Toyota hybrid car battery

Figure 1: Nickel-metal-hydride battery of a Toyota hybrid car.

The cells (orange color) are supported to allow forced air-cooling. The battery is placed behind the back seat.

Courtesy of the Toyota Museum, Nagaya, Japan

One of the critical battery requirements for hybrid applications is longevity. Rechargeable batteries for consumer products typically last for two to three years. This short service life is no major drawback with cell phones, laptops and digital cameras because the devices get obsolete quickly. At $2,000 to $3,000 per battery pack, the replacement cost of an HEV battery would constitute a major expense.

 

Most batteries for HEV are guaranteed for eight years. To meet this long service life, the cells are optimized for longevity and not size and weight, as is the case with portable applications. Since the battery runs on wheels, the increased weight and size is not too critical.

A NiMH for an HEV can be charged and discharged 1,000 times if done at an 80% depth-of-discharge. In a hybrid vehicle, a full discharge occurs seldom except if the owner lives on a mountain and requires all available battery power to commute home. Such a routine would add stress to the battery and the life would be shortened. In most other application, the hybrid car only uses 10% of the rated battery capacity. This allows thousands of charge/discharge cycles. Batteries in satellites use a similar system in which the battery discharges less than 10% during a satellite night. NASA achieves this by over-sizing the battery.

 

One of the limitations of NiMH is moderate energy conversion efficiency. This translates to the battery getting hot on charge and discharge. The charge efficiency is best at 50-70% state-of-charge. Above 70% the battery cannot absorb the charge well and much of the charging energy is lost in heat. Operating a battery with a partial charge requires a larger mass that lowers the energy-to-weight ratio and efficiency.

 

The Japanese car manufacturers have tried several battery chemistries, including going back to lead acid. Today, the focus is on lithium-ion. The cobalt-based lithium-ion is one of the first chemistries in the lithium family and offers a very high energy density. Unfortunately, this battery system cannot deliver high currents and is restricted to portable applications.

 

HEV manufacturers are experimenting with manganese (spinel) and phosphate versions. These lithium-ion systems offer an extremely low internal resistance, deliver high load currents and accept rapid charge. Unlike the cobalt version, the resistance stays low throughout the life of the battery. To verify the characteristic of manganese-based lithium-ion, a research lab applied 30,000 discharge/charge cycles over a period of seven years. Although the capacity dropped from 100% to 20%, the cell retained its low internal resistance. The drawback of manganese and phosphate is lower energy density but these systems provide 20% more capacity per weight than NiMH and three times more than lead acid. Figure 2 illustrates the energy densities of the lead, nickel and lithium-ion systems. It should be noted that lithium-ion systems have the potential of higher energy densities but at the cost of lower safety and reduced cycle life.

battery chemistries

Figure 2: Energy densities of common battery chemistries.

Lithium-cobalt enjoys the highest energy density. Manganese and phosphate systems are thermally more stable and deliver higher load currents than cobalt.

The Lithium-ion systems are promising candidates for both the HEV and plug-in HEV but require more research. Here are some of the roadblocks that need to be removed:

Durability: The buyer requests a warranty of ten years and more. Currently, the battery manufacturer for hybrid electric vehicles can only give eight years on NiMH. The longevity of lithium-ion has not yet been proven and honoring eight years will be a challenge.

Cost: If the $2,000 to $3,000 replacement cost of a nickel-metal-hydride pack is prohibitive, lithium-ion will be higher. These systems are more expensive to produce than most other chemistries but have the potential for price reductions through improved manufacturing methods. NiMH has reached the low cost plateau and cannot be reduced further because of high nickel prices.

Safety: Manganese and phosphate-based lithium-ion batteries are inherently safer than cobalt. Cobalt gets thermally unstable at a moderate temperature of 150°C (300°F). Manganese and phosphate cells can reach 250°C (480°F) before becoming unsafe. In spite of the increased thermal stability, the battery requires expensive protection circuits to supervise the cell voltages and limit the current in fail conditions. The safety circuit will also need to compensate for cell mismatch that occurs naturally with age. The recent reliability problems with lithium-ion batteries in portable devices may delay entry into the HEV market.

Availability: Manufacturers of manganese and phosphate cells can hardly keep up with the demand. A rapid increase of lithium for HEV batteries would put a squeeze on battery production. With 7 kg (15 lb) of lithium per battery, there is talk of raw material shortages. Most of the known supplies of lithium are in South America, Argentina, Chile and Bolivia.

The plug-in hybrid electric vehicle (PHEV)

Imagine a plug-in electric vehicle that can go 20 miles (32 km) with a single charge from the electrical outlet at home. There is no pollution and the neighbors won’t hear you coming and going because the vehicle is totally silent. With the absence of gas tax, the road system is yours to use for free. Or is it?

As good as this may sound, the savings will be small or non-existent because of the battery. Dr. Menahem Anderman, a leading expert on advanced automobile batteries, says that we still have no suitable battery for the plug-in HEV and that the reliability of lithium-ion technology for automotive applications has not yet been proven. Unlike the ordinary HEV that operates on shallow charges and discharges, the plug-in HEV is in charge depletion mode that requires deep discharges. To obtain an acceptable driving range, the PHEV battery will need to be five times larger than the HEV battery. With an estimated life span of 1000 full charge and discharge cycles, the battery would need to be replaced every three years. At an estimated $10,000 per battery replacement, the anticipated cost savings would be quickly exhausted.

Modern cars do more than provide transportation; they also include auxiliary devices for safety, comfort and pleasure. The most basic of these auxiliaries are the headlights and windshield wipers. Most buyers would also want heating and air-conditioning systems. These amenities are taken for granted in gasoline-powered vehicles and will need to be used sparingly in a PHEV.

Analysts give another 10 years before a viable plug-in HEV will be available. The promise of a clean-burning fuel cell car is still vivid in our memory. Analysts now estimate 20 years before the fuel cell is ready for mass-produced cars. There are rumors that the fuel cell may never make it into an ordinary car. If this is true, a dream will go down in history with the steam-powered airplane of the mid 1800s that was simply too cumbersome to fly.

The paradox of the hybrid vehicle

At the Advanced Automotive Battery Conference in Hawaii, a delegate member challenged a maker of HEVs with the claim that a German diesel car can get better fuel economy than the hybrid. The presiding speaker, being a trained salesman, flatly denied this notion. There is some truth to his claim, however. On the highway, the diesel car is indeed more fuel-efficient but the HEV has the advantage in city driving. Power boost for fast acceleration and regenerative breaking are advantages that the German diesel does not offer.

Someone then asked, “What would happen if the HEV depletes its batteries while driving up a long mountain pass? Will the car have enough power?” The answer was that the car would make it with the IC engine alone but the maneuverability would be restraint. To compensate for this eventuality, some HEV manufacturers offer SUVs featuring a full-sized IC motor of 250 hp and an electrical motor at 150 hp; 400 hp in total. Such a vehicle would surly find buyers, especially if the government provides grant money for being ‘green.’ It’s unfortunate that the buyers of a small car or the commuters taking public transport won’t qualify for such a handout.

Conclusion

We anticipate that lithium-ion will eventually replace nickel-metal-hydride in hybrid electric vehicles but short service life, high manufacturing costs and safety issues will stand in its way today. We need to remind ourselves that the automotive market can only tolerate a marginal cost increase for a new battery technology. In terms of added capacity, lithium-ion offers only a 20% increase in energy density per weight over nickel-based systems. The nickel-metal-hydride has proven to work well in current HEVs and a new chemistry would need to offer definite advantages over present systems to find buyers.

Toyota, Honda and Ford are leading in HEV technology. Other major automakers are expected to offer competitive models by 2010. Currently, Panasonic EV Energy and Sanyo supply over 90% of the HEV batteries. Both companies are also developing lithium-ion batteries.
While Japan and Korea are focusing on manganese systems, the USA is experimenting with phosphate, the chemistry that made the A123 Systems famous. Europe is relying on clean-burning diesel. These engines are so clean that they won’t even stain a tissue that is placed on the exhaust pipe. BMW is working on a zero emission hydrogen car.

Time will tell who will be the winner in the race for cleaner, more fuel-savvy vehicles and longer-living cars. In terms of longevity, the diesel would be the winner today. We hope that future batteries will one-day have the endurance to match or exceed the robust diesel engine.

 

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Industrial Applications

Industrial applications have unique power needs and the choice of battery is important. While consumer products demand high energy density to obtain slim and elegant designs, industry focuses on durability and reliability. Industrial batteries are commonly bulkier than those used in consumer products but achieve a longer service life.

Batteries are electro-chemical devices that convert higher-level active materials into an alternate state during discharge. The speed of such transaction determines the load characteristics of a battery. Also referred to as concentration polarization, the nickel and lithium-based batteries are superior to lead-based batteries in reaction speed. This attribute reflects in good load characteristics.

Discharge loads range from a low and steady current flow of a flashlight to intermittent high current bursts in a power tool, to sharp current pulses on digital communications equipment, laptops and cameras. In this paper we evaluate how the various battery chemistries perform in a given application.

What’s the best battery for video cameras?

Nickel-cadmium batteries continue to power a large percentage of professional cameras. This battery provided reliable service and performs well at low temperature. nickel-cadmium is one of the most enduring batteries in terms of service life but has only moderate energy density and needs a periodic full discharge.

The need for longer runtimes is causing a switch to nickel-metal-hydride. This battery offers up to 50% more energy than nickel-cadmium. However, the high current spikes drawn by digital cameras have a negative affect and the nickel-metal-hydride battery suffers from short service life.

There is a trend towards lithium-ion. Among rechargeables, this chemistry has the highest energy density and is lightweight. A steep price tag and the inability to provide high currents are negatives.

The 18650 cylindrical lithium-ion cell offers the most economical power source. “18” defines the cell’s diameter in millimeters and “650” the length. No other lithium-ion cell, including prismatic or polymer types, offers a similar low cost-per-watt ratio.

Over the years, several cell versions of 18650 cells with different Ah ratings have emerged, ranging from 1.8Ah to well above 2Ah. The cells with moderate capacities offer better temperature performance, enable higher currents and provide a longer service life than the souped up versions.

The typical 18650 for industrial use is rated at 2Ah at 3.60 volts. Four cells are connected in series to obtain the roughly 15 volts needed for the cameras. Paralleling the cells increases the current handling by about 2A per cell. Three cells in parallel would provide about 6A of continuous power. Four cells in series and three in parallel is a practical limit for the 18650 system.

Lithium-ion requires a protection circuit to provide safe operations under all circumstances. Each cell in series is protected against voltage peaks and dips. In addition, the protection circuit limits each cell to a current about 2A. Even if paralleled, the current of a lithium-ion pack is not high enough to drive digital cameras requiring 10 to 15A peak current. Tests conducted at Cadex Electronics have shown that the 18650 allows short current peaks above the 2A/cell limit. This would allow the use of lithium-ion on digital cameras, provided the current bursts are limited to only a few seconds.

What’s the best battery for still cameras?

The power requirement of a professional digital camera is sporadic in nature. Much battery power is needed to take snapshots, some with a powerful flash. To view the photo, the backlit color display draws additional power. Transmitting a high-resolution image over the air depletes another portion of the energy reserve.

Most non-professional cameras use a primary lithium battery. This battery type provides the highest energy density but cannot be recharged. This is a major drawback for professional use. Rechargeable batteries are the answer and lithium-ion fits the bill but faces similar challenges to the video cameras.

battery for still cameras

What is the best battery for medical devices?

One of the most energy-hungry portable medical devices is the heart defibrillator. The battery draws in excess of 10 amperes during preparation stages. Several shocks may be needed to get the patient’s heart going again. The battery must not hamper the best possible patient care.
battery for medical devices
Most defibrillators are powered by nickel-cadmium. nickel-metal-hydride is also being used but there is concern of short service life. In a recent study, however, it was observed that a defibrillator battery cycles far less than expected. Instead of the anticipated 200 cycles after two years of seemingly heavy use, less than 60 cycles had been delivered on the battery examined. ‘Smart’ battery technology makes such information possible. With fewer cycles needed, the switch to higher energy-dense batteries becomes a practical alternative.

Sealed lead-acid batteries are often used to power defibrillators intended for standby mode. Although bulky and heavy, the Lead-acid has a low self-discharge and can be kept in prolonged ready mode without the need to recharge. Lead-acid performs well on high current spurts. During the rest periods the battery disperses the depleted acid concentrations back into the electrode plate. Lead-acid would not be suitable for a sustained high load.

The medical industry is moving towards lithium-ion. The robust and economical 18650 cells make this possible. The short but high current spurts needed for defibrillators are still a challenge. Paralleling the cells and adding current-limiting circuits that allow short spikes of high current will help overcome this hurdle.

What is the best battery for power tools?

Power tools require up to 50 amperes of current and operate in an unfriendly environment. The tool must perform at sub zero temperatures and endure in high heat. The batteries must also withstand shock and vibration.

Most power tools are equipped with nickel-cadmium batteries. nickel-metal-hydride has been tried with limited success. Longevity is a problem but new designs have improved. lithium-ion is too delicate and could not provide the high amperage. Lead-acid is too bulky and lacks persistent power delivery. The power tool has simply no suitable alternatives to the rugged and hard-working nickel-cadmium.

In an attempt to pack more energy into power tools, the battery voltage is increased. Because of heavy current and application at low temperatures, cell matching is important. Cell matching becomes more critical as the number of cell connected in series increases. A weak cell holds less capacity and is discharged more quickly than the strong ones. This imbalance causes cell reversal on the weak cell if the battery is discharged at high current below 1V/cell. An electrical short occurs in the weak cell if exposed to reverse current and the pack needs to be replaced. The higher the battery voltage, the more likely will a weak cell get damaged.

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Lithium Advantages In Your Bass Boat

The anticipation of a morning bite can make it difficult to sleep at night. As you wait for the sun to peak over the horizon you run over everything in your checklist. All your rods are rigged, and you have every bait from a topwater frog to a Texas rigged senko tied on. Every bit of your terminal tackle is stowed perfectly, and you even remembered to pack a lunch. Except that one major piece of the puzzle that you forgot suddenly hits you and you realize that you never charged your trolling motor batteries. Luckily, you made the decision to replace those old lead acid batteries you had for lithium powered batteries and you can be charged up enough by sunrise to salvage the trip. A major sigh of relief for those that live and die by the water and the time they get to spend making cast after cast.

 

Every component of a boat must work together in order for you to create those unforgettable bites that every angler chases. A fault in your boat’s system can quickly turn a picture-perfect day into a nightmare. Often, we think about all the accessories we want to add to our bass boats to make them more functional and to improve our odds of catching those elusive giants, yet we pay less mind to the power plant of our technologies. At Li-ion we want to make it very simple and clear as to why lithium batteries are the best choice for your bass boat.

A bass boat needs reliable marine batteries as they are necessary for both starting and running your fishing machine. Not all batteries serve the same purpose as some are intended specifically for producing cranking power for engine startups and others are used exclusively for running your trolling motor. Essentially, starting batteries discharge a large amount of energy for a short period of time making them perfect for starting your outboard engines. Deep cycle batteries on the other hand, discharge small amounts of energy over an extended period of time. Regardless, lithium batteries offer solutions to every angler’s needs.

 

Time to charge is a major factor of each and every battery. Lithium, however, charges significantly faster than lead acid. Plain and simple. Our lithium batteries can be charged in as fast as an hour, but we recommend using a charge rate that charges them in 2-5 hours. This means that the moment of panic of whether you plugged your batteries in is long gone and you can be confident that you’ll be ready come morning. Some may wonder if leaving the battery in a state of partial charge will damage its performance or overall longevity and quite frankly the answer is, no. Lithium batteries are partial charge tolerant making them perfect for the on the go or maybe even the forgetful angler.

 

At first glance the cost of switching to lithium batteries may seem impractical in comparison to lead acid but when you break down the details, they paint a very different picture. Lithium batteries last up to 10 times longer than their lead acid counterparts and they still provide 80% capacity after 2000 cycles. This means that you don’t have to bring in a forklift every couple of years to haul out those absurdly heavy chunks of lead you have at the stern of your boat (you don’t actually need a forklift but you get the point). It is this same weight that has reduced your fuel economy and your time to plane. Every pound you add to the boat makes you draft that much deeper and can ultimately affect the ride and performance. Lithium batteries have 50-60% less weight than lead acid batteries and in some cases the weight savings from switching to lithium batteries can exceed 100 pounds. This amount of weight taken off your stern will improve both your range and wide-open throttle numbers for those days when you want to hammer down.

 

For the days when the bite rages from dawn to dusk or even the days when you grind it out for that one single bite, lithium power will be with you all the way. Quite simply, lithium has more hours of power. Lithium iron phosphate provides more usable capacity than lead acid. With 25-50% higher capacity than lead acid batteries with full power throughout discharge lithium batteries eliminate the voltage sag that is all too common with lead acid. All your accessories will be uninterrupted, and you can continue to max out that five fish limit you were working on. As the sun begins to drop after a full day on the water you won’t have to worry about anything except coming up with an excuse as to why you couldn’t make it home for your family dinner on time.

 

 

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Series Vs. Parallel Connections Explained

Series Vs. Parallel Connections Explained

 

While researching lithium batteries, you’ve probably seen the terms series and parallel mentioned. We frequently get asked the question, “what’s the difference between series and parallel”, “can Li-ion batteries be connected in series” and similar questions. It can be confusing if you’re new to lithium batteries or batteries in general, but hopefully we can help simplify it.

Let’s start at the beginning…your battery bank. The battery bank is the result of connecting two or more batteries together for a single application (i.e. a sailboat). What does joining more than one battery together accomplish? By connecting the batteries, you either increase the voltage or amp-hour capacity, and sometimes both, ultimately allowing for more power and/or energy.

The first thing you need to know is that there are two primary ways to successfully connect two or more batteries: The first is called a series connection and the second is called a parallel connection.

Series connections involve connecting 2 or more batteries together to increase the voltage of the battery system, but keeps the same amp-hour rating. Keep in mind in series connections each battery needs to have the same voltage and capacity rating, or you can end up damaging the battery. To connect batteries in series, you connect the positive terminal of one battery to the negative of another until the desired voltage is achieved. When charging batteries in series, you need to utilize a charger that matches the system voltage. We recommend you charge each battery individually, with a multi-bank charger, to avoid imbalance between batteries.

In the image below, there are two 12V batteries connected in series which turns this battery bank into a 24V system. You can also see that the bank still has a total capacity rating of 100 Ah.

Parallel connections involve connecting 2 or more batteries together to increase the amp-hour capacity of the battery bank, but your voltage stays the same. To connect batteries in parallel, the positive terminals are connected together via a cable and the negative terminals are connected together with another cable until you reach your desired capacity.

A parallel connection is not meant to allow your batteries to power anything above its standard voltage output, but rather increase the duration for which it could power equipment. It’s important to note that when charging batteries that are connected in parallel, the increased amp-hour capacity may require a longer charge time.

In the example below, we have two 12V batteries, but you see the amp-hours increase to 200 Ah.

Now we get to the question, “Can Li-ion batteries be connected in series or parallel?”

Standard Product Line: Our standard lithium batteries can be wired in either series or parallel based on what you’re trying to accomplish in your specific application. Li-ion’s data sheets indicate the number of batteries that can be connected in series by model. We typically recommend a maximum of 4 batteries in parallel for our standard product, however there may be exceptions that allow for more depending on your application.

It’s important to understand the difference between parallel and series configurations, and the effects they have on your battery bank’s performance. Whether you’re seeking an increase in voltage or amp-hour capacity, knowing these two configurations is vastly important in maximizing your lithium battery’s life and overall performance.

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Choosing The Right Batteries For Your Overland Vehicle

Himax-Golf-car-battery

If you are interested in overland vehicles, it pays to figure out the best way to power it. By taking the time to find the right battery setup for your overland vehicle, you’ll be able to hit the terrain without worry. When you are in need of a new system, these are the tips you’ll need to consider.

Finding the Right Battery Setup for Overland Vehicles

Lithium batteries are used in a number of applications, including marine vehicles, overland vehicles, golf carts and more.

Here’s what you need to know before making a purchase:

 

1.Understand the Specifications

As you research various batteries, you will need to look into its specifications to ensure it’s the right fit for your application and power needs. Learning about each battery’s capabilities will allow you to make the proper choice for your overlanding vehicle.

Each overlanding outfit will have different requirements and for some a single battery unit may be plenty while for others they may require a multi-unit setup for those long trips to the middle of nowhere. Everything must be considered from the weight of the unit to its power output. We understand that the details matter when it comes to exploration and adventure.

2.Consider the Maintenance That Comes with Your Battery

Anytime you’re using batteries on a regular basis, you’ll need to be fully aware of the maintenance that comes with the territory. This means understanding the status of the battery’s power before long trips and making sure that the connections are secure.

 

Thankfully, lithium batteries require virtually no maintenance, so your maintenance costs and obligations will be low. Both on and off-season maintenance is minimal making your experience with lithium worry and stress free. This is yet another reason why they are an excellent investment.

3.Decide on What Power Needs You Have

Quite possibly the most important consideration to make when looking to install a new system or upgrade from your existing battery system is what kind of power you will need.

This will depend on the type of vehicle you own, how often you drive it, and what you may be powering with your lithium deep cycle battery. In terms of voltage, you might purchase batteries that are 12.8 Volts, 25.6 Volts, 51.2 Volts, and other power measurements.

You should also consider amperage and other measurements that come into play when you are in the market for a new battery setup.

When you use deep cycle batteries, they’ll still power your electronic devices when you’re stopped. This is particularly useful when you’re in undeveloped areas with no hookups or access to power sources. Regardless, LiFeP04 batteries offer a solution to every enthusiast’s needs.

Himax-Golf-car-battery

4.Weigh the Pros and Cons of Lead-Acid vs. Lithium

It’s important to think about the features you require in a battery for your expeditions, then decipher which battery chemistry is ideal for your needs.

Lead-acid batteries may still dominate the market, but many overland adventurers are moving to lithium batteries instead because they’re a superior alternative to traditional batteries. The benefits of choosing LiFePO4 over lead-acid for any application are numerous. And, when it comes to your overland vehicle, there are specific advantages that make lithium overland batteries the ideal choice. They weigh less, offer more usable capacity, they’re safe and they have a much longer life cycle, up to ten times longer. Lead-acid, on the other hand, can weigh twice as much as lithium and requires far more maintenance while still producing less usable capacity over its range. Lithium out performs lead-acid in nearly every category and is an excellent long term investment for those looking to get off the grid.

5.Decide How Much You Want to Pay

Of course, you will need to consider the price whenever you are in the market for a new battery setup.

There are several types of batteries, including FLA, GEL, AGM and LiFePO4, so it pays to figure out your budget in advance, while also having an idea of how much one of these new batteries will cost you. While lithium batteries have a higher upfront cost, the true cost of ownership is far less than lead-acid when considering life span and performance. Changing batteries less often means fewer replacement and labor costs. These savings make lithium batteries a more valuable long-term investment than lead-acid batteries.

If you are going to have a repair shop handle the installation, be sure to get cost estimates of both the battery itself and the labor for the installation.

 

6.Consider Waterproofing and Other Protective Features

Finally, make sure that you get a listing of all the features that come with the battery.

A number of overland battery setups come with waterproofing, which will protect it from rain and changes in moisture. You’ll want to buy a battery that has thickly insulated, anti-corrosive cables as well. This will allow you to keep the battery intact and flowing with the current.

See what connectors it comes with and see if you can trade-in your old battery before buying a new one.

RV-Car-Battery

Buy the Perfect Battery for Your Overland Vehicle

When you consider a battery setup for overland vehicles, these are the tips you need to be aware of.

We’ve got you covered when you are in the market for any kind of battery setup that you need.

Consider these tips and buy a deep cycle lithium battery that is perfect for your overland adventures.

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The Best Golf Cart Batteries: Lithium Vs. Lead Acid

car-battery

The golf cart market is evolving as more and more people are taking advantage of their versatile performance. For decades, deep-cycle flooded lead-acid batteries have been the most cost effective means to power electric golf cars. With the rise of lithium batteries in many high-power applications, many are now looking into the advantages of LiFePO4 batteries in their golf cart.

While any golf cart will help you get around the course or neighborhood, you need to make sure it has enough power for the job. This is where lithium golf cart batteries come into play. They’re challenging the lead-acid battery market due to their many benefits that make them easier to maintain and more cost-effective in the long run.

Below is our breakdown of the advantages of lithium golf cart batteries over lead-acid counterparts.

48v-ev-battery

Carrying Capacity

Equipping a lithium battery into a golf cart enables the cart to significantly increase its weight-to-performance ratio. Lithium golf cart batteries are half the weight of a traditional lead-acid battery, which shaves off two-thirds of the battery weight a golf cart would normally operate with. The lighter weight means the golf cart can reach higher speeds with less effort and carry more weight without feeling sluggish to the occupants.

 

The weight-to-performance ratio difference lets the lithium-powered cart carry an additional two average-sized adults and their equipment before reaching carrying capacity. Because lithium batteries maintain the same voltage outputs regardless of the battery’s charge, the cart continues to perform after its lead-acid counterpart has fallen behind the pack. In comparison, lead acid and Absorbent Glass Mat (AGM) batteries lose voltage output and performance after 70-75 percent of the rated battery capacity is used, which negatively affects carrying capacity and compounds the issue as the day wears on.

 

No Maintenance

One of the major benefits of lithium batteries is that they require no maintenance whatsoever, whereas lead-acid batteries regularly need to be checked and maintained. This ultimately results in saved man hours and the extra costs of maintenance tools and products. The lack of lead-acid means that chemical spills are avoided and the chance of downtime on your golf car is drastically reduced.

 

Battery Charging Speed

Regardless if you’re using a lead-acid battery or a lithium battery, any electric car or golf cart faces the same flaw: they have to be charged. Charging takes time, and unless you happen to have a second cart at your disposal, that time can put you out of the game for a while. A good golf cart needs to maintain consistent power and speed on any course terrain. Lithium batteries can manage this without a problem, but a lead-acid battery will slow the cart down as its voltage dips. Plus after the charge has dissipated, it takes an average lead-acid battery roughly eight hours to recharge back to full. Whereas, lithium batteries can be recharged up to 80 percent capacity in about an hour, and reach full charge in less than three hours.

 

Plus, partially-charged lead-acid batteries sustain sulfation damage, which results in significantly reduced life. On the other hand, lithium batteries have no adverse reaction to being less than fully charged, so it’s okay to give the golf cart a pit-stop charge during lunch.

72V 200Ah

Eco-Friendly

Lithium batteries put less strain on the environment. They take significantly less time to fully charge, resulting in using less energy. They do not contain hazardous material, whereas lead-acid batteries, as the name suggests, contain lead which is harmful to the environment.

 

Battery Cycle Life

Lithium batteries last significantly longer than lead-acid batteries because the lithium chemistry increases the number of charge cycles. An average lithium battery can cycle between 2,000 and 5,000 times; whereas, an average lead-acid battery can last roughly 500 to 1,000 cycles. Although lithium batteries have a high upfront cost, compared to frequent lead-acid battery replacements, a lithium battery pays for itself over its lifetime. Not only does the investment in a lithium battery pay for itself over time, but big savings can be made in the way of reduced energy bills, maintenance costs, and possible repairs that would otherwise need to be made to heavy lead-acid golf cars. They also just perform better overall!

 

Are Lithium Golf Cart Batteries Compatible?

Golf carts designed for lead-acid batteries can see a significant performance boost by swapping the lead-acid battery to a lithium battery. However, this second wind can come at an instillation cost. Many lead-acid equipped golf carts need a retro-fit kit to operate with a lithium battery, and if the cart manufacturer doesn’t have a kit, then the cart will need modifications to operate with a lithium battery.